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How do “Dock leaves” work to reduce itching from stinging nettles?

Dock leaves are the wild cure to stinging nettles, right? Everyone knows this. But how do they stop the stinging? What's the mechanism?
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What animal might uproot and relocate a newly-transplanted sedum?

My husband transplanted a sedum to an area under our bird feeders about ten feet away. The plant is 6 inches wide, 14 inches long, and the hole was approximately 10 inches deep. After removing it, he ...